Theoretical study of dipeptide complexes of copper(II)
نویسندگان
چکیده
The L,L-Phe-Leu-Cu(II), L,L-Leu-Phe-Cu(II), L,L-Phe-Met-Cu(II), and L,L-Met-Phe-Cu(II) systems were studied using molecular modelling. The results obtained, which are in good agreement with results obtained by potentiometric studies show a significant increase in stability of copper complexes, when an aromatic residue is located in C-terminal (compared to the L,L-dipeptides containing the same amino acid residues), this phenomenon is attributed to the interaction between the d-orbital of copper and the p-electrons of the aromatic ring. 2006 Elsevier B.V. All rights reserved.
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